Hypervalent Iodine Catalyst Grants Access to 1,4-Difunctionalized Fluorinated Olefins
نویسندگان
چکیده
Key words fluorination - dienes hypervalent iodine difunctionalization
منابع مشابه
Terminal olefins to linear α,β-unsaturated ketones: Pd(II)/hypervalent iodine co-catalyzed Wacker oxidation-dehydrogenation.
Development of a mild (35 °C, no Brønsted acids) tandem Wacker oxidation-dehydrogenation of terminal olefins was accomplished using palladium(II) and hypervalent iodine co-catalysis. The reaction affords linear aryl and alkyl α,β-unsaturated ketones directly from readily available terminal olefins in good yields (average 75% per step) with excellent functional group tolerance and chemo- and ste...
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ژورنال
عنوان ژورنال: Synfacts
سال: 2023
ISSN: ['1861-194X', '1861-1958']
DOI: https://doi.org/10.1055/s-0042-1753263